In reply to Frank4short: Yep WL Gore discovered it accidentally, but the company he was working for (DuPont maybe?) wouldn't accept the potential of his discovery, so he quit and started his own company to exploit his discovery.
Goretex itself is expanded (stretched in a specific set of atmospheric condidtions) PTFE (poly tetra fluro ethylene).
Currently it's available in 3 different forrms - Paclite Shell, Performance Shell and Pro Shell. The easiest way to look at these three is by looking at requirements for each category.
Paclite garments are "2-layer" garments. Basically the outer "face" fabric (the stuff you see on the outside of the jacket), the goretex membrane inside, and then a thin protective layer (almost a chemical treatment) to keep oils from damaging the membrane itself. For a jacket to be labeled "Paclite" it must be using this specific "2-layer" technology, and it must weight less than 500g.
Proshell is the best waterproof/breathable fabric out there currently. Rather than using a painted or glued protective layer as in Paclite, a third woven layer (called the Micro Grid Woven Backer) is attached to the inside of the goretex (ie the bit that it up against your inner layers). The MGB is unique, and is the thing that currently sets Pro Shell apart (and above, in my opinion) everything else out there. Event, Goretex XCR etc use what is called a tricott mesh backer. There is no comparison between the micro grid woven backer and the tricott mech, and Pro Shell is the only fabric using the MGB. The MGB is lighter, smoother (less internal friction), more durable, more breathable and faster drying. Couple this with micro seam tolerances (reducing the bulk of the garment by wasting less material in the overlap of a seam) and mini seam tape (increasing the breathable area of the garment), and Pro Shell is obviously the best of what is currently available.
Performance shell is pretty much the category that is used at the catch all for everything else. More traditional 3-layer jackets (ie goretex with a tricott mesh backer) are classed as Performance shell, as are jackets that don't have the micro seam tolerances. Even a jacket that is using Paclite technology but weighs over 500g gets a Performance Shell tag (see the Mountain Hardwear Xenon jacket - its face fabric was heavy duty, meaning the whole jacket weighed in at about 520g, so it missed out on a Paclite tag. Although labeled Performance Shell, it was effectively the burliest Paclite jacket in the world.
Goretex XCR is not considered a current technology for clothing anymore. It's still used on footwear, but any new season Goretex clothing will be labeled Paclite, Performance Shell, or Pro Shell.
Sorry for the long winded reply. I hope this makes sense to everyone.