In reply to Ethan Thomas:
I had to come seeking similar advice when i got my 5.10 Teams.
I got them at street shoe size and they've been pretty hideous. Same reason of having my toe knuckles rammed into the toe box.
I dont get to climb much but over the course of a month and a bit they're starting to get useful. I still dont like falling on my feet in them as the toe bend hurts most but I've gone from taking them off every 10 minutes to having them on for most of the session, up to 3 hours. As mentioned previously, tightening the velcro up a lot, illogically, does seem to help, as does sitting with my heels out for a bit.
I know nothing of Evolve sizing but you do ultimately have to make a call as to whether they can or will be able to stretch enough for you to put up with them.