In reply to Antigua:
The highway code defines night as half an hour after sunset, which gives an idea of when its seen as needed for seeing. Then side lights are required from sunset. So you need lights at 7:35.
Personally I would want them prior to that. Depending on if its overcast anything up to an hour or so before (generally in flashing mode).
Plus you have how fast you want to ride and whether its offroad, especially under tree cover.