In reply to DeanD:
Used them quite a bit. Best if you have a thin sock under them - stops the slightly clammy feeling. Definitely needs to be well under zero.
The main benefit comes when you are out for multiple successive days as they stop the boot's insulation from getting ever damper from your perspiration. Your feet don't get too hot and if you use thin inners then you just have another pair to use for the second day. If you are away from civilisation for several days, the thin socks dry out quickly in your sleeping bag as they get damp rather than sodden.