In reply to Alan James - UKC:
Gripfill is you best bet on this on.
It is a waterproof adhesive along the lines of the resin you use for bolts.
Just squirt it in the whole and keep going until it starts to come out.
Wet your finger and then smooth over until you get a reasonable looking surface.
You can get lots of this type of stuff in Wickes it goes under the name of Liquid nails or No more nails but i prefer Gripfill as it is the original and best.
Or you could just buy a bag of sand and a bag of cement and do it properly.
Hope this helps.