In reply to Ali:
A rule of thumb I have heard is the "rule of 12", that is, no more than 12 people pulling on a rope. Or 6 with x2 mechanical advantage etc.
For a tug of war, 5v5, the rope gets the same force on it as 5 people pulling on it if it were tied off on a post. So as 5 is much less than 12, I don't think there is any risk of it breaking, not by a long way.
It might stretch more than a typical tug of war rope mind...