In reply to richprideaux:
You know that feeling when you think about something for few minutes, draw conclusions and write some gibberish on the forum because you think you had a conversation about something you were thinking on your own? Yeah, that's what I just did. Sorry about that.
What I wanted to say was that you can get a more accurate than 6 figure grid reference if you use some software (that's obvious!). Figuring out six-figure grid out of a map without a ruler won't be accurate (my Silva compass has both 1:25k and 1:50k rulers, but god Harvey maps are using 1:40k). However, if you can get an accurate grid reference before setting off, then you can have more than 100mx100m resolution.