In reply to NottsRich:
> I thought that might be the case... Thanks for confirming. I had considered taking the stem out and quickly shoving a bung in the hole, with a few towels on standby.
It'll spray mucky water *everywhere* no matter how fast you are. Drain it.
> Any way of predicting what size/type it will be?
Strip it while the plumber's merchants are open and have a back-up plan (blanking caps!) if you can't get the parts you want that day because you'll likely lose hot water while your central heating is drained and in bits while the shops are closed and that makes you unpopular at home as I've learned over the years. New valves won't be expensive but putting it all back together leak free is in my experience an annoying iterative process involving several sessions of draining, filling, bleeding, testing, swearing....!
jk