In reply to Worried, of Sheffield:
Yeah, I definitely read about this, too, and about the freezer experiment.
From what I recall, the boots are particularly at risk after being left out at a bivi (they get a lot colder than when your feet are in them.
The newer plastic, I recall reading, is less prone to this problem, but can't remember when it changed.
Do remember wondering if I should put my Koflach shells in the freezer, then tap the toe with a hammer. But thinking this would ruin them, and for use in Scotland they wouldn't get this cold, certainly not with me wearing them, so wondering if it was a dumb thing to do.
In the end I bought some Sportiva Nepal Tops. Unless you're skint, or have specific reasons for needing plastics, modern leathers are so good, there's not going back, I reckon. A glimmer of good news if you plastics are at risk....