In reply to eddy-on-the-rocks:
We use the Twynau for nav training for Central Beacons MRT, largely because our base is just down the road. It's a perfectly good area, but there are other better areas around: it's a bit scrappy underfoot at times. Watch out for the gas pipeline which makes compass use interesting! I'd park at Asda and walk up.
As Ross says, Llangynidr is good for night nav (I prefer the west side of the B road, it's slightly less boggy), and Cwm Cadlan (north of the B road) is also very good.
Shakeholes make excellent targets for both day and night nav, you're very unlikely to go plunging down one as long as you're not running.