In reply to Richard Bradley:
Adhesion (stickyness) is the force needed to seperate two different contacting objects perpendiculary, like pulling bluetack
vertically up from a surface.
Friction is a velocity dependant property, defining the
reistanace to lateral translation of one object against the
other
I guess that high friction prevents the boot slipping when
pushed downwards by your weight against the rock.
High adhesion would prevent your foot moving vertically up from a flat surface e.g the floor.
Guess that in reality, climbing invovles a hybrid situation,
where the force between boot and rock would be at an angle were elements of both adhesion and friction would come into play?
Also, the rubbing boots togther thing is measuring cohesion, i.e adhesion between the same two materials.