In reply to cezza:
> DVI is digital, VGA is analogue. So in an ideal world you will get a better / sharper image using DVI at higher resolutions.
Indeed, and, assuming the monitor is LCD, it will have an ADC to convert analogue to digital used by the LCD display, so you're better off bypassing the DAC in the video card and the ADC in the monitor, and driving the LCD digital stream directly from the DVI interface.
As you say, you may not notice the difference, but at least you know that you've eliminated two possible sources of signal degradation in the video path...