In reply to MargieB:
as above, you could connect the orange and try each one of the white ones in turn, connecting any wrong one wont do any harm, another way if you have access to something that can ring it,is to bare the end of the orange wire and all the whites and ring your number, when you short the correct white with the orange the ringing will trip and you will know when you have the correct white.
re putting it on your tongue will indeed work but its not for the faint hearted, its only 50 volts dc but it will sting a bit, also if someone rings in while you are doing it then that's going to sting a lot as its 90vlts.
p.s are you sure about the orange wire as that's normally pair 2, colour coding is white blue pair 1, white orange pair 2 white green pair 3 white brown pair 4 and white grey pair 5.