In reply to Martin Davies (KCLMC):
Sounds like the PU (most likely, but could be silicone) coating is dying, in which case washing is unlikely to help.
Whether this death is to be expected is open to question, and depends what you mean by 'good use'.
Google has some useful hits:
http://www.google.co.uk/search?hl=en&biw=1280&bih=554&q=polyure...
Including one suggestion (reportedly from Sea-to-summit) that PU-coated tents should be stored unrolled...
Then there's this, from MSR:
http://cascadedesigns.com/MSR/FAQ/Tents
"Never pack or store your tent if it is wet, damp or dirty. Although we use the best polyurethane waterproofing available, prolonged exposure to moisture causes hydrolysis which, in turn, causes the waterproof layer to break down, becoming soft, sticky and no longer waterproof. Storing a wet tent for as little as 24 hours in warm weather is also likely to start the process of mildew forming on the fabric. Mildew will cause your tent to stain, smell and will also lead to the premature breakdown of the waterproof coating. Mildew and moisture damage are not covered under the Limited Warranty."