In reply to sam_seed:
Google for excel pasword cracking, you should find many tools / services. Just make sure that your firewall is good as some of the sites may not be particularly wholesome.
If the workbook is protected so that you cannot open it, you may not have much luck uless you pay for the service, or use a brute force attack which can take time. If a sheet is protected or macros are protected, then there are many around. I use an addin called simply enough "Password Remover".
Passware excel key and vba key demos are free and give you the first few letters, if the password is simple, you could then try a dictionary attack.